The ignition delay times of n-C
7H
16/O
2/N
2 and i-C
8H
18/O
2/N
2 mixtures with different fuel, O
2, and N
2 concentrations were calculated using a detailed chemical kinetic model generated by KUCRS. Ignition delay times with high initial temperatures, where ignition process bypasses low-temperature oxidation, were analyzed. The dependence of ignition delay time on fuel concentration, O
2 concentration, heat capacity per unit fuel concentration, and third body concentration was distilled to establish a power law equation for ignition delay time using the scaling exponents for these parameters. For n-C
7H
16, the scaling exponents for fuel concentration, O
2 concentration, heat capacity, and third body concentration were 0.54, 0.29, – 0.38, and 0.08, respectively, and E/R was 14400 K. For i-C
8H
18, the scaling exponents for fuel concentration, O
2 concentration, heat capacity, and third body concentration were 0.40, 0.76, – 0.47, and 0.00, respectively, and E/R was 11900 K.
View full abstract