CF
3I gas, which is one of promising SF
6 substitutions, is investigated from the view point of by-product generated in gas discharge, since its global warming potential (GWP) is quite low and its insulation performance is equivalent or superior to SF
6 gas. The insulation performance of CF
3I gas is examined through measuring sparkover voltage in various electric fields and flashover voltage on the surface of insulating material together with analyzing by-products of CF
3I gas. Gas chromatography analysis shows that C
2F
6, C
2F
4, CHF
3, C
3F
8, C
3F
6, and C
2F
5I are generated by the sparkover and the flashover. The sparkover voltage after 1300 times sparkover in uniform electric field is decreased by 11%. The flashover voltage for a virgin insulator in CF
3I gas is almost equal to that in SF
6 gas. The flashover voltage in CF
3I gas is, however, 0.6 times lower than that in SF
6 gas, when the number of surface flashover is increased.
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