Journal of The Surface Finishing Society of Japan
Online ISSN : 1884-3409
Print ISSN : 0915-1869
ISSN-L : 0915-1869
Size of Dispersed TiO2 Particles and the Codeposition
Fumio YAMAGUCHINobuyuki KOURAHideyuki NEGISHIYasushi IDEMOTO
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1998 Volume 49 Issue 5 Pages 525-529

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Abstract
Dispersed TiO2 particles form an adsorption equilibrium on the surface of a cathode in the electrolyte. Equilibrium is strongly affected by the surfactant concentration, which is related to the zeta potential of dispersed TiO2 particles. Particles having a large zeta potential disperse stably without aggregation, because the repulsive force between particles is large. Particles having a small zeta potential aggregate and produce rough particles, decreasing the number of particles, that collide with and are adsorbed on the cathode. Rough particles easily desorbed from the cathode because of their weight, decreasing the amount of codeposited particles.
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