Journal of the Japan Society for Composite Materials
Online ISSN : 1884-8559
Print ISSN : 0385-2563
ISSN-L : 0385-2563
Research paper
Mechanism of Weak Bond Formation in CFRP Adhesive Joints
Tetsuya MORIMOTOAkihiro FUJIMOTOHisaya KATOHHisashi KUMAZAWA
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2020 Volume 46 Issue 4 Pages 121-129

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Abstract

This work aims to explain the mechanisms of weak bond formation in CFRP epoxy adhesive joints by studying aqueous NaCl mist contamination. First, a mechanism of epoxy ring consumption by Cl ion was proposed to explain the reduction in covalent bond density at the adhesion interphase, as a function of pH alkaline drift. Second, double cantilever beam test (DCB test) was applied to CFRP joint samples with aqueous NaCl mist contamination at the adhesion interphase to prove a weak bond triggered by Cl ion contamination. Third, contamination layer thickness was estimated by substituting the data into the drift function. Obtained nanometer-thin thickness indicates that the stirring flow of the adhesive dissipates the layer to form a standard joint, while steady flow keeps the layer to form a weak-bond joint. Therefore, 1) Cl ion contamination at the adhesion interphase and 2) the handling in the adhesion process explain the statistical aspect of weak bond formation in the production line of CFRP adhesive joints.

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© 2020 The Japan Society for Composite Materials
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