Journal of the Japan Society of Powder and Powder Metallurgy
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
Magnetic Properties of Sr-Nd-Co M-type Ferrite Fine Particles Prepared by Chemical Coprecipitation Method
Hiroshi YamamotoTetsuro Kobayashi
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JOURNAL OPEN ACCESS

2003 Volume 50 Issue 8 Pages 642-647

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Abstract
A single-phase Sr-Nd-Co M-type ferrite fine particles have been produced by the chemical coprecipitation and heat treatment method for the sample having a formula {(SrO⋅n/2(Fe2O3))}100-x-y(Nd2O3)x(CoO)y (n = 7.0, x= 1.0-10.0, y =1.0-10.0). The chemical reagents used are FeCl3⋅6H2O, SrC12⋅6H2O, NdC13⋅6H2O, and CoCl2⋅6H2O. A solution containing Sr2+, Fe3+, Nd3+, and Co2+ is poured into a solution of NaOH (pH=13.0).
Then the precipitated products are boiled for 2 h and they are carefully washed and dried. The obtained fine particles are heated at a temperature between 950 and 1100°C for 2h in air to get a single-phase Sr-Nd-Co M-type ferrite fine particles. The most prominent magnetic properties have been observed for the sample with the compotion of { SrO⋅3.5(Fe2O3) }94.0(Nd2O3)2.0(CoO)4.0; they are as follows: σs=89.5 × 10-6 Wb⋅m/kg (71.2 emu/g), σr=45.3 × 10-6 Wb⋅m/kg (36.0 emu/g), HcJ=490.0 kA/m (6.16 kOe), α (σr) =-0.20 %/°C, α (HcJ)=0.08 %/°C and Tc=465.3°C.
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