A new compound has been synthesized by iodine intercalation on Bi2212 single crystal under the existence of Mo. Its lattice parameter along the c-axis was 1.842 nm which is shorter than that of I, Bi₂Sr₂CaCu₂O_y (1.900 nm). The fluorescence X-ray analysis microscope data showed that only I₂ was intercalated in Bi2212. The thermogravimetric curve showed weight loss of 7.6%. The temperature dependence of the out-of-plane normal resistivity was changed from semiconductor-like to metallic-like after intercalation. The transition temperature(onset) of the intercalated compound was 83 K lower than that of Bi2212 by 12K.