Journal of the Japan Society of Powder and Powder Metallurgy
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
Raman Scattering of Pb-Based High-Tc Superconducting Oxides
Masato KakihanaMinoru OsadaIchiro NagaiTakashi NojiMasatsune KatoYoji Koike
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JOURNAL OPEN ACCESS

1999 Volume 46 Issue 9 Pages 999-1003

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Abstract
The Raman spectra of (Pb2Cu)Sr2Y1-xCaxCu2O8+δ (Pb3212), (Pb2Cu)Sr0.9La1.1CuO6+δ (Pb3201), and (Pb0.5Cu0.5)Sr2YCu2O7+δ (Pb1212) were studied and vibrational assignments in harmony with the layer stacking sequencies found in these Pb-based high-Tc superconducting oxides were proposed. In particular, the assignment of the 480-and 580-cm-1 Raman bands to oxygen in the PbO and SrO layers, respectively, was unambiguously established. In the case of Pb3212 we found that the intensities of modes connected to the CuO2-plane vibrations decreased with increasing carrier concentration. This effect was attributed to the increased metallic screening in the CuO2 planes that can be expected in the hole-rich Ca-doped samples.
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