Abstract
The Raman spectra of (Pb2Cu)Sr2Y1-xCaxCu2O8+δ (Pb3212), (Pb2Cu)Sr0.9La1.1CuO6+δ (Pb3201), and (Pb0.5Cu0.5)Sr2YCu2O7+δ (Pb1212) were studied and vibrational assignments in harmony with the layer stacking sequencies found in these Pb-based high-Tc superconducting oxides were proposed. In particular, the assignment of the 480-and 580-cm-1 Raman bands to oxygen in the PbO and SrO layers, respectively, was unambiguously established. In the case of Pb3212 we found that the intensities of modes connected to the CuO2-plane vibrations decreased with increasing carrier concentration. This effect was attributed to the increased metallic screening in the CuO2 planes that can be expected in the hole-rich Ca-doped samples.