Journal of the Japan Society of Powder and Powder Metallurgy
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
Dimensional Change and Fe-Zn Phase Formation during Preparation of Zn Bonded Sm2Fe17Nx Magnet
Kazuhiko MajimaKatsuhiro MatsukadoShigeru KatsuyamaHiroshi Nagai
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JOURNAL OPEN ACCESS

1994 Volume 41 Issue 11 Pages 1336-1340

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Abstract
The sintering behavior of the compacts composed of Sm2Fe17Nx and 30wt%Zn was studied by DSC, the dilatometric measurement and XRD, and the magnetic properties of the sintered compacts were also investigated by using VSM. The dilatometric measurement revealed that the compacts exhibit an expansion beginning at 643K during sintering, and it was confirmed that this expansion was due to the formation of FeZn4 and/or Fe3Zn7. The results of VSM show that magnetic properties were improved with the increase of heat treatment temperature from 623K ; the optimum coercivity(iHc) of 0.948T was obtained by the heat treatment at 747K for 4h. Beyond 763K, however, the magnetic properties decreased due to the decomposition of Sm2Fe17Nx into α-Fe and SmN.
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