Journal of the Japan Society of Powder and Powder Metallurgy
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
Synthesis of Ceramics Composites by Mechanical Alloying of Ti and Si3N4
Yuichi IwaseTomoaki KogaNichihiko Nagumo
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JOURNAL OPEN ACCESS

1992 Volume 39 Issue 3 Pages 174-178

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Abstract
Mixtures of Si3N4, and Ti were milled with a high energy ball mill under argon atmosphere and successively sintered with a hot press. The resulted reaction products were fine mixtures of Ii5 Si3, TiSi2, IN and Si, their fractions varying according to initial compositions, milling time and sintering temperatures. The temperatures at which sintering proceeded was much lower than that for sintering of Si3N4, again depending upon compositions and milling time. The density of sintered products was high enough with hardness comparable to that of TiN. Sound indentations without cracking were noted.A model based on kinematical rather than thermodynamical equilibrium aspect was presented to explain the dependence of reaction products on process parameters.
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