Journal of the Japan Society of Powder and Powder Metallurgy
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
Paper
Pulsed Electric-current Pressure Sintering of Spinel Type (Fe, Mn)Al2O4 Ferrites and their Physical Property Evaluation
Masahiro UEDAMasaki KATOKen HIROTA
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JOURNAL OPEN ACCESS

2014 Volume 61 Issue 4 Pages 171-178

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Abstract
Single-phase spinel type FeAl2O4 and Mn – doped solid solutions of (Fe1−xMnx)Al2O4 (0 < x ≤ 1.0) powders have been prepared by solid state reaction at 900 ˚C for 6 h in 1.0 % H2 – bal.N2 using reactive fine powders of α – Fe2O3 (particle size of 0.1 µmφ), γ – Al2O3 (about 10 nmφ) and MnO (about 0.15 µmφ). Afrer the powder characterization using XRD, they were densified using pulsed electiric-curuent pressure sintereing (PECPS) at 1050 ˚C for 10 min under 50 MPa in Ar atmossphere. Thus fabricated dense ceramics, having single-phase spinel strucure with the relative desity ≥ 97.0 %, were evaluated by XRD, SEM, and a SQUID magnetometer. They showed antiferromagnetic properties, except for x = 1.0, i.e., MnAl2O4 (paramagnetic), and at the compositions of x: 0.4~0.6, Mn – doped solid solutions ceramics revealed moderate high magnetic susceptibility.
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© 2014 by Japan Society of Powder and Powder Metallurgy

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